STRUCTURE OF ANATO(1,4,7,LL-TETRAAZACYCLOTETRADECANE)COPPER(II) THIOCYANATE

Authors
TAHIROV TH LU TH LAN WJ CHUNG CS
Citation
Th. Tahirov et al., STRUCTURE OF ANATO(1,4,7,LL-TETRAAZACYCLOTETRADECANE)COPPER(II) THIOCYANATE, Acta crystallographica. Section C, Crystal structure communications, 49, 1993, pp. 1908-1910
Citations number
7
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
49
Year of publication
1993
Part
11
Pages
1908 - 1910
Database
ISI
SICI code
0108-2701(1993)49:<1908:SOAT>2.0.ZU;2-Y
Abstract
There are two independent similar copper(II) complexes in the asymmetr ic unit. The coordination about copper(II) in each complex forms a dis torted square pyramid with the tetraamine N atoms equatorial and the N atom of the isothiocyanato group axial. The two five-membered rings a re in skew forms and the two six-membered rings in chair forms. The is othiocyanato groups are almost linear. Hydrogen bonds help stabilize t he crystal structure.