Low-temperature photoluminescence spectra of n-InSe layered single cry
stals were studied in the temperature range 10-210 K. Photoluminescenc
e of n-InSe showed peaks at 1.334, 1.306, 1.288, and 1.232 eV at 10 K.
These four peaks were attributed to radiative recombination of the di
rect free excitons, an impurity-band transition, a donor-acceptor reco
mbination channel, and the transition within an impurity-vacancy compl
ex, respectively. To determine the temperature dependence of direct ba
nd gap of n-InSe, we estimated the exciton binding energy to be 15 meV
by assuming an isotropic approximation for the anisotropy parameter g
amma = 1. From these peak positions and the estimated band gap, the do
nor and acceptor levels associated with these centers were estimated t
o be approximately 43 and 18 meV, respectively. The temperature variat
ions of the peak energy and linewidth of the excitons in n-InSe were e
xplained by taking into account both the exciton-acoustic-phonon and t
he exciton-optical-phonon interactions. Below approximate to 60 K, the
se variations are due mainly to exciton scattering by acoustic phonons
via the deformation potential in InSe. (C) 1998 Elsevier Science Ltd.