IS(MU-(N-[(METHYLTHIO)PHENYLMETHYLENE]-METHANAMINE 5,5-HEXAFLUOROPENTANE-2,4-DIONATO-O,O')NICKEL(II)]

Authors
DICKMAN MH WARD JP VILLAMENA FA CRIST DR
Citation
Mh. Dickman et al., IS(MU-(N-[(METHYLTHIO)PHENYLMETHYLENE]-METHANAMINE 5,5-HEXAFLUOROPENTANE-2,4-DIONATO-O,O')NICKEL(II)], Acta crystallographica. Section C, Crystal structure communications, 54, 1998, pp. 929-930
Citations number
8
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
54
Year of publication
1998
Part
7
Pages
929 - 930
Database
ISI
SICI code
0108-2701(1998)54:<929:I5>2.0.ZU;2-K
Abstract
The title compound, [Ni-2(C5HF6O2)(4)(C9H11NOS)(2)], crystallizes as a centrosymmetric dimer containing two Ni(hfac)(2) moieties bridged by two nitrone ligands (hfac is the 1,1,1,5,5,5-hexafluoropentane-2,4-dio nate anion), The Ni ... Ni distance is 3.2904(5) Angstrom, with Ni-O-n itrone distances of 2.0776 (12) and 2.0974 (12) Angstrom. The average Ni-O-hfac distance is 2.022 (16) Angstrom.