O. Jarjayes et al., A PHENOXO-BRIDGED DIGALLIUM(III) COMPLEX WITH A LIGAND DERIVED FROM N'-BIS(CARBOXYMETHYL)AMINO]-METHYL)-4-METHYLPHENOL, Acta crystallographica. Section C, Crystal structure communications, 54, 1998, pp. 931-933
The title complex, triaqua-1 kappa(2)O,2 kappa O-hydroxo-2 kappa N'-(2
-hydroxylato-5-methyl-m-phenylenedimethylene- kappa(2)O:O)bis[N-(carbo
xylatomethyl-kappa O)glycinato-kappa(2)N, 0](5-)}-digallium(III) 5.5-h
ydrate, [Ga-2(OH)-(C17H17N2O9)(H2O)(3)].5.5H(2)O, contains two octahed
rally-coordinated Ga-III atoms. A hydroxyl group in the coordination s
phere of one Ga atom corresponds to a water molecule in the second. Th
e hydrogen-bond network includes an intramolecular hydrogen bond.