HYL-5A,6,7,8,9,9A-HEXA-HYDRO-1H-1,5-BENZODIAZEPINE

Citation
Rf. Jordan et al., HYL-5A,6,7,8,9,9A-HEXA-HYDRO-1H-1,5-BENZODIAZEPINE, Acta crystallographica. Section C, Crystal structure communications, 54, 1998, pp. 1030-1033
Citations number
17
Categorie Soggetti
Crystallography
ISSN journal
01082701
Volume
54
Year of publication
1998
Part
7
Pages
1030 - 1033
Database
ISI
SICI code
0108-2701(1998)54:<1030:H>2.0.ZU;2-K
Abstract
The title compound, C11H18N2, packs in the solid state with one molecu le in the asymmetric unit, but with the chiral molecule disordered ove r two orientations related by twofold rotation. Thus, the molecule is the average of these two orientations, with the amine H atom present w ith half occupancy at each N atom and 'pseudo-aromatic' character in t he N-C-C-C-N moiety of the diazepine ring. The molecules are linked to form infinite chains parallel to the c axis via NH N hydrogen bonds a cross crystallographic twofold axes, with N N 3.224 (3) and 3.110 (3) Angstrom (the hydrogen-bonded H atom is disordered).