RO-1H,3H-PYRROLO[1,2-C]OXAZOL-3-YLIDENE)-1-PROPENE 1,1-DICARBONITRILEAND PHENYL)-2,6-BIS(METHYLTHIO)PYRIDINE-3-CARBONITRILE

Authors
GEORGE M DAS S ASHOKAN CV RATH NP GEORGE MV
Citation
M. George et al., RO-1H,3H-PYRROLO[1,2-C]OXAZOL-3-YLIDENE)-1-PROPENE 1,1-DICARBONITRILEAND PHENYL)-2,6-BIS(METHYLTHIO)PYRIDINE-3-CARBONITRILE, Acta crystallographica. Section C, Crystal structure communications, 54, 1998, pp. 1033-1036
Citations number
10
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
54
Year of publication
1998
Part
7
Pages
1033 - 1036
Database
ISI
SICI code
0108-2701(1998)54:<1033:R1>2.0.ZU;2-8
Abstract
The reaction of 3-aryl-2-cyano-5,5 -bis (methylthio)penta-2,4-dienenit rile, (1), with L-(-)-2-hydroxymethylpyrrolidine, (2), gave two types of product, the normal substitution product, (3), and a pyridine deriv ative, (4). The structures of two representative examples, c]-oxazol-3 -ylidene)-1-propene-1,1-dicarbonitrile, (3a), as its hemibenzene solva te, C17H15N3O.0.5C(6)H(6), and 4-(4-methoxyphenyl)-2,6-bis(methylthio) pyridine-3-carbonitrile, (4b), C15H14N2OS2, have been unambiguously e stablished by X-ray crystallographic analysis. The molecular packing o f (4b) involves loosely held dimers, with S1...S1' distances of 3.424( 1) Angstrom.