AN EXPERIMENTAL AND CALCULATED STUDY OF INTRAMOLECULAR HYDROGEN-ATOM TRANSFER IN DIETHYLENE GLYCOL BIS(ALLYL CARBONATE)

Authors
QURESHI A SCHIESSER CH
Citation
A. Qureshi et Ch. Schiesser, AN EXPERIMENTAL AND CALCULATED STUDY OF INTRAMOLECULAR HYDROGEN-ATOM TRANSFER IN DIETHYLENE GLYCOL BIS(ALLYL CARBONATE), Journal of chemical research. Synopses (Print), (6), 1998, pp. 328
Citations number
18
Categorie Soggetti
Chemistry
Journal title
Journal of chemical research. Synopses (Print) → ACNP
ISSN journal
03082342
Issue
6
Year of publication
1998
Database
ISI
SICI code
0308-2342(1998):6<328:AEACSO>2.0.ZU;2-N
Abstract
Deuterium labeling experiments and molecular orbital (MNDO) calculatio ns indicate that 1,6-homolytic hydrogen transfer from C8 to C3 is not responsible for the products observed when diethylene glycol bis(allyl carbonate) is treated with tert-butoxyl radicals in the presence of 1 ',1',3',3'-tetramethylisoindolinyl-2'-oxyl.