SYNTHESIS OF OLIGO-ENYNES USING [FE(ALKENE)(CO)(N)] SCAFFOLDS - Z E-SELECTIVE WITTIG-TYPE AND HORNER-TYPE OLEFINATION REACTIONS OF BETA-CARBONYL GROUPS IN ETA(4)-DIENE AND GAMMA-CARBONYL GROUPS IN ETA(2)-ALKENE COMPLEXES OF IRON/

Authors
BOHMER J SCHOBERT R
Citation
J. Bohmer et R. Schobert, SYNTHESIS OF OLIGO-ENYNES USING [FE(ALKENE)(CO)(N)] SCAFFOLDS - Z E-SELECTIVE WITTIG-TYPE AND HORNER-TYPE OLEFINATION REACTIONS OF BETA-CARBONYL GROUPS IN ETA(4)-DIENE AND GAMMA-CARBONYL GROUPS IN ETA(2)-ALKENE COMPLEXES OF IRON/, Journal of chemical research. Synopses (Print), (7), 1998, pp. 372
Citations number
33
Categorie Soggetti
Chemistry
Journal title
Journal of chemical research. Synopses (Print) → ACNP
ISSN journal
03082342
Issue
7
Year of publication
1998
Database
ISI
SICI code
0308-2342(1998):7<372:SOOU[S>2.0.ZU;2-O
Abstract
beta-Oxo-dienetricarbonyliron complexes 4 and gamma-oxo-alkenecarbene complexes 5 undergo olefinations with a wide range of phosphonates and phosphoranes with high E- or Z-selectivity and give the free oligo-en (yn)es or carbamates, respectively, upon oxidative demetalation.