ON THE USE OF REMOVABLE STERIC BUTTRESSES IN CYCLOADDITION REACTIONS

Authors
CHOONY N DADABHOY A SAMMES PG
Citation
N. Choony et al., ON THE USE OF REMOVABLE STERIC BUTTRESSES IN CYCLOADDITION REACTIONS, Journal of the Chemical Society. Perkin transactions. I (Print), (13), 1998, pp. 2017-2021
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Perkin transactions. I (Print) → ACNP
ISSN journal
0300922X
Issue
13
Year of publication
1998
Pages
2017 - 2021
Database
ISI
SICI code
0300-922X(1998):13<2017:OTUORS>2.0.ZU;2-J
Abstract
Use of bulky protecting groups, such as the trityl group, can be utili sed to encourage cycloaddition reactions that otherwise do not proceed . Thus N-allylfurfurylamines, bearing the appropriate N-protecting gro up, can thermally cyclise; subsequent removal of the protecting group produces the thermodynamically unstable, free amine.