Jt. Baek et al., INTERFACIAL REACTION BETWEEN ALUMINUM METAL AND BORON-DOPED POLYSILICON IN A PLANAR TYPE ANTIFUSE DEVICE, JPN J A P 1, 37(5A), 1998, pp. 2451-2454
The interfacial reaction between Al metal and boron-doped polysilicon
was investigated to understand the mechanism of link formation in the
planar type antifuse with a polysilicon pad and two Al electrodes. In
the antifuse, the Si-Al alloy filament with a low resistance was forme
d only on the boron-doped polysilicon pad, not on the phosphorus-doped
or undoped polysilicon pads. After annealing Al/boron-doped polysilic
on at 400 degrees C for 20 min, an Al-B compound (AlB2) was found by t
he reaction between Al metal and solute borons at the grain boundaries
of polysilicon using Auger electron spectroscopy, X-ray diffractomete
r, and X-ray photoelectron spectroscopy. In the planar type antifuse d
evice, the formation of AlB2 at the grain boundaries might act as a se
ed for the conductive filament formation by supplying Al from the posi
tive electrode. After forming a low resistance Si-Al alloy filament, i
t grows toward the negative electrode by the reaction between supplied
Al and highly reactive solute borons segregated at the grain boundari
es.