Y. Neo et al., EPITAXIAL-GROWTH OF ALUMINUM ON SILICON SUBSTRATES BY METALORGANIC MOLECULAR-BEAM EPITAXY USING DIMETHYL-ETHYLAMINE ALANE, JPN J A P 1, 37(5A), 1998, pp. 2602-2605
In this paper, the growth process of aluminum on a silicon substrate b
y metalorganic molecular beam epitaxy using dimethylethylamine alane h
as been described. The crystallographic orientation of the aluminum gr
ains strongly depends on the substrate temperature. The epitaxial sing
le crystalline (111) Al grains grow on a(lll) Si substrate at a substr
ate temperature between 450 and 500 degrees C. The bi-crystalline (110
) Al grains grow on a (100) Si substrate at the substrate temperature
between 350 and 450 degrees C. For a (100) Si substrate, the orientati
on of Al is related to the reconstruction of the Si substrate. Further
more, the selective growth of Al into 1.5-mu m-diameter via-holes is s
hown to be possible.