S. Faetti, ON THE K13 SURFACE-LIKE ELASTIC-CONSTANT AN EXPERIMENTAL-METHOD TO TEST DIFFERENT THEORETICAL-MODELS, Liquid crystals, 15(6), 1993, pp. 807-818
Oldano and Barbero showed that, due to the presence of the surface-lik
e elastic constant K13 in the expression of the elastic free energy de
nsity, F2, in a nematic liquid crystal, the functional F2 is unbounded
from below and thus it is impossible to find an equilibrium director
distortion. In particular, they showed that the surface-like elastic c
onstant favours a discontinuity of the director-field at the interface
s. In recent years two quite different theoretical approaches have bee
n proposed to eliminate the mathematical difficulties related to the K
13 problem. Barbero et al., expanded the free energy functional F up t
o the fourth order in the director derivatives and showed that the min
imization problem becomes mathematically well posed. A strong subsurfa
ce director distortion on a length scale of the order of the molecular
length is predicted by using this approach. This point has been criti
zed by V. Pergamenshchik who considers the subsurface strong distortio
n as an artefact of theory and proposes an alternative method to accou
nt for the effect of K13. This method is virtually coincident with tha
t already proposed by Hinov on the basis of an a priori assumption. In
this paper we discuss some direct consequences of these two different
approaches and we propose two simple experimental measurements which
should lead to different results depending on which model is the corre
ct one, allowing in this way a test of the different theoretical model
s.