AN ALTERNATIVE GENERATION OF A 13.14-CARBON-CARBON TRIPLE BOND IN PROSTANOIDS

Authors
KLAR U DEICKE P PLETSCH A
Citation
U. Klar et al., AN ALTERNATIVE GENERATION OF A 13.14-CARBON-CARBON TRIPLE BOND IN PROSTANOIDS, Synthetic communications, 23(22), 1993, pp. 3185-3189
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthetic communications → ACNP
ISSN journal
00397911
Volume
23
Issue
22
Year of publication
1993
Pages
3185 - 3189
Database
ISI
SICI code
0039-7911(1993)23:22<3185:AAGOA1>2.0.ZU;2-F
Abstract
A novel HBr elimination method for the introduction of a 13.14-triple bond into the prostanoid framework starting from readily available vin yl bromides is described. The transformation can be performed even on sensitive compounds in the presence of various functional groups in sy nthetically useful yields.