V. Crescenzi et al., CIRCULAR-DICHROISM OF AQUEOUS-SOLUTIONS AND GELS OF PARTIAL BENZYL-ESTERS OF THE POLYSACCHARIDE GELLAN, Die Makromolekulare Chemie. Macromolecular symposia, 76, 1993, pp. 95-97
Three partial benzyl esters of gellan have been studied by means of ci
rcular dichroism spectroscopy in aqueous tetramethylammonium chloride
solution and in the gel state (aqueous NaCl). Thermal stability of the
solution ordered chain states as well as of the gels, maximal in the
case of gellan, markedly decreases with increasing degree of esterific
ation.