DEUTERIUM-ISOTOPE EFFECTS ON THE C-13 CHEMICAL-SHIFTS OF CYCLOOCTANONE-2-D

Authors
JUNG M
Citation
M. Jung, DEUTERIUM-ISOTOPE EFFECTS ON THE C-13 CHEMICAL-SHIFTS OF CYCLOOCTANONE-2-D, Bulletin of the Korean Chemical Society, 19(8), 1998, pp. 836-840
Citations number
9
Categorie Soggetti
Chemistry
Journal title
Bulletin of the Korean Chemical Society → ACNP
ISSN journal
02532964
Volume
19
Issue
8
Year of publication
1998
Pages
836 - 840
Database
ISI
SICI code
0253-2964(1998)19:8<836:DEOTCC>2.0.ZU;2-N
Abstract
The intrinsic and equilibrium isotope effects on the C-13 NMR chemical shift of the cyclooctanone-2-D were investigated. Equilibrium constan ts and changes in the free energies, enthalpy, entropy, which are deri ved from the temperature dependence of the isotope shifts, are reporte d for this isotopomer.