U. Schwertmann et H. Stanjek, STIRRING EFFECTS ON PROPERTIES OF AL GOETHITE FORMED FROM FERRIHYDRITE, Clays and clay minerals, 46(3), 1998, pp. 317-321
Minerals in surface environments form in both turbulent and non-turbul
ent systems. This study compares the properties of Al goethite formed
from ferrihydrite at 60 degrees C in 0.3 M KOH with and without mechan
ical stirring. Compared to the static system, stirring increased cryst
al order and needle thickness, decreased unit cell edge length a, but
not b and c, reduced the separation between the 2 OH-bending vibration
s, increased Al substitution and promoted hematite formation.