SONOCHEMICAL DECOMPOSITION OF LIQUID BENZENE - FORMATION OF CARBON FINE PARTICLES BY ADDITION OF CCL4

Citation
R. Katoh et al., SONOCHEMICAL DECOMPOSITION OF LIQUID BENZENE - FORMATION OF CARBON FINE PARTICLES BY ADDITION OF CCL4, Nippon kagaku kaishi, (8), 1998, pp. 530-534
Citations number
15
Categorie Soggetti
Chemistry
Journal title
ISSN journal
03694577
Issue
8
Year of publication
1998
Pages
530 - 534
Database
ISI
SICI code
0369-4577(1998):8<530:SDOLB->2.0.ZU;2-T
Abstract
Sonochemical graphitization of liquid benzene has been studied. Sonoch emical reaction proceeds through production and collapse of a bubble i nduced by ultrasonics. During the collapse, high temperature and high pressure conditions can be realized and the degradation of molecules o ccur, then, fine particles are formed. In order to produce carbon fine particles from liquid benzene, we attempted hydrogen abstraction by c hlorine atoms which are produced through degradation of carbon tetrach loride. The formation of graphitic carbon could be confirmed through R aman spectroscopy.