R. Katoh et al., SONOCHEMICAL DECOMPOSITION OF LIQUID BENZENE - FORMATION OF CARBON FINE PARTICLES BY ADDITION OF CCL4, Nippon kagaku kaishi, (8), 1998, pp. 530-534
Sonochemical graphitization of liquid benzene has been studied. Sonoch
emical reaction proceeds through production and collapse of a bubble i
nduced by ultrasonics. During the collapse, high temperature and high
pressure conditions can be realized and the degradation of molecules o
ccur, then, fine particles are formed. In order to produce carbon fine
particles from liquid benzene, we attempted hydrogen abstraction by c
hlorine atoms which are produced through degradation of carbon tetrach
loride. The formation of graphitic carbon could be confirmed through R
aman spectroscopy.