STRUCTURE AND SPECTROSCOPIC PROPERTIES OF BORANE-1-TRIMETHYLSILYLPIPERIDINE

Authors
MEDINA JR HUERTAS R SODERQUIST JA HUANG SD
Citation
Jr. Medina et al., STRUCTURE AND SPECTROSCOPIC PROPERTIES OF BORANE-1-TRIMETHYLSILYLPIPERIDINE, Journal of chemical crystallography, 28(4), 1998, pp. 309-311
Citations number
6
Categorie Soggetti
Crystallography,Spectroscopy
Journal title
Journal of chemical crystallography → ACNP
ISSN journal
10741542
Volume
28
Issue
4
Year of publication
1998
Pages
309 - 311
Database
ISI
SICI code
1074-1542(1998)28:4<309:SASPOB>2.0.ZU;2-A
Abstract
As a new borane source for hydroboration, borane-1-trimethylsilylpiper idine (1) was synthesized from the reaction of diborane with 1-trimeth ylsilylpiperidine. The molecular structure of 1 was unambiguously dete rmined by a combination of H-1, C-13 and B-11 NMR spectra and X-ray si ngle crystal analysis. X-ray crystallographic data for 1: Orthorhombic Pnma (#62), a = 6.4476(6) Angstrom, b = 10.503(1) Angstrom, c = 6.058 (2) Angstrom, V = 1087.4(2) Angstrom(3), Z = 4.