A NOVEL MONOMERIC TIN(II) PHOSPHATE, [N(C2H5NH3)3](3-)CENTER-DOT-4H2O, CONNECTED THROUGH HYDROGEN-BONDING() [SN(PO4) (HPO4)](3)

Authors
AYYAPPAN S CHEETHAM AK NATARAJAN S RAO CNR
Citation
S. Ayyappan et al., A NOVEL MONOMERIC TIN(II) PHOSPHATE, [N(C2H5NH3)3](3-)CENTER-DOT-4H2O, CONNECTED THROUGH HYDROGEN-BONDING() [SN(PO4) (HPO4)](3), Journal of solid state chemistry (Print), 139(1), 1998, pp. 207-210
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Journal of solid state chemistry (Print) → ACNP
ISSN journal
00224596
Volume
139
Issue
1
Year of publication
1998
Pages
207 - 210
Database
ISI
SICI code
0022-4596(1998)139:1<207:ANMTP[>2.0.ZU;2-K
Abstract
The tin(II) phosphate, [N(C2H5NH3)(3)](3+) [Sn(PO4)(HPO4)](3-) 4H(2)O, contains monomeric Sn-2(PO4)(2)(HPO4)(2) units which form a hydrogen- bonded network with the TREN amine (TREN = N(C2H5NH3)(3)(3+)); triclin ic, space group P1 (no. 2), a = 9.579(1), b = 10.507(1), c = 10.976(1) Angstrom; alpha = 72.93(1)degrees, beta = 78.03(1)degrees, gamma = 69 .82(1)degrees, V = 984.2(1) Angstrom(3), Z = 2, The Sn2P2O4 core of th is unit is a common structural feature of open-framework tin phosphate s and may play a role as a building block for this class of materials. (C) 1998 Academic Press.