ESTIMATING THE MIGRATION CONSTITUENT OF THE CURRENT DURING ELECTROLYTIC GROWTH OF LEAD DENDRITES

Authors
POTAPOV OA RUDOI VM MURASHOVA IB
Citation
Oa. Potapov et al., ESTIMATING THE MIGRATION CONSTITUENT OF THE CURRENT DURING ELECTROLYTIC GROWTH OF LEAD DENDRITES, Russian journal of electrochemistry, 34(8), 1998, pp. 750-755
Citations number
8
Categorie Soggetti
Electrochemistry
Journal title
Russian journal of electrochemistry → ACNP
ISSN journal
10231935
Volume
34
Issue
8
Year of publication
1998
Pages
750 - 755
Database
ISI
SICI code
1023-1935(1998)34:8<750:ETMCOT>2.0.ZU;2-N
Abstract
The growth of a dendrite deposit of lead is studied in fluoborate and nitrate electrolytes containing 0.75 M Pb2+ at various supporting elec trolyte concentrations. The results are used to determine migration co nstituents of discharge currents at dendrite tops. It is found that th e absolute value of the migration flow towards dendrite tops may be es sential even in the presence of an excess of a foreign electrolyte. Th is effect is due to a high current density at the tops caused by spher ical diffusion.