IMPEDANCE ANALYSIS OF ELECTRODEPOSITED INSULATING POLYPYRROLE

Authors
Citation
S. Komaba et T. Osaka, IMPEDANCE ANALYSIS OF ELECTRODEPOSITED INSULATING POLYPYRROLE, Journal of electroanalytical chemistry [1992], 453(1-2), 1998, pp. 19-23
Citations number
16
Categorie Soggetti
Electrochemistry,"Chemistry Analytical
Journal title
Journal of electroanalytical chemistry [1992]
ISSN journal
15726657 → ACNP
Volume
453
Issue
1-2
Year of publication
1998
Pages
19 - 23
Database
ISI
SICI code
Abstract
To develop a general quantitative method of analyzing the process of e lectrodeposition of high resistance materials, the electrical resistan ce of electrochemically deposited insulating polypyrrole (PPy) film wa s measured in situ by ac impedance. By considering the potential drop across the PPy film during its formation by constant potential electro lysis, the growth of the insulating PPy film was analyzed, and an equi valent circuit describing the interfacial structure was proposed. (C) 1997 Elsevier Science S.A. All rights reserved.