Dust extinction observations and the calculation of gas-dust dynamics
indicate that in dense clumps of molecular clouds dust grains coagulat
e efficiently. We set up a detailed model for the dust coagulation pro
cess in dense cores of molecular clouds without beginning star formati
on. We took into account the effects of thermal, turbulent, gravitatio
nal motion, motion from incidential particle asymmetries, grain rotati
on, charges, and the accretion of molecules onto the particles. For mo
st effects, we developed new formalisms. For the first time, we explic
itly considered the irregularity and changing fluffiness of the cluste
rs produced in the coagulation process. The basis for this treatment w
as an independent numerical simulation of the structure of such aggreg
ates. Here, we considered especially the behaviour of aggregates small
er than the fractal limit and composed of subgrains with a spectrum of
sizes. We fitted the structure parameters by analytic functions which
were used in the final model for the coagulation of the interstellar
particles. With this model we carried out numerous simulations of the
evolution of dust grain distributions in dense cores. The particles we
re characterized by two parameters, the particle mass and a quantity r
elated to the internal density of the particles. Different gas densiti
es, clump models, accretion rates, and initial grain size distribution
s were investigated. It was found that the main force driving the aggr
egation of dust particles in dense clumps is turbulence at gas densiti
es below 10(8) H-atoms per cm3 and Brownian motion at higher densities
. The coagulation velocity is considerably influenced by electric char
ges on the grains. Both dust coagulation and ice accretion lead to a r
apid growth of the smallest particles whereas the upper grain size lim
it is only slightly shifted. The resulting size and density distributi
on will be narrow on the grain mass scale but broad in the internal de
nsity parameters of the coagulates. The total opacity of the resulting
distributions of fluffy dust agglomerates was calculated using effect
ive-medium theories combined with a core-mantle model for the aggregat
e particles. The far infrared absorptivity is enhanced by the factor 3
(at 200 mum) in the first steps of the coagulation process and hardly
influenced by the further coagulation. For gas densities between 10(6
) and 10(9) CM-3 and timescales below 10(5) yrs, the coagulation proce
ss is efficient in changing the optical properties of the dust particl
es but not in the production of large heavy particles.