The radial dynamics of a spherical gas bubble in a compressible shear-
thinning liquid is studied by means of a singular perturbation method
to first order in the bubble-wall Mach number. The Williamson rheologi
cal model is adopted to describe the shear-thinning characteristic of
liquid viscosity. The equation of motion for the bubble radius, the eq
uation of the natural frequency of the bubble and the pressure equatio
n are derived. Numerical calculations are presented using the experime
ntal data for two polymer aqueous solutions, viz. HEC and CMC solution
s, and water. It is found that the shear-thinning characteristic of li
quid viscosity strongly influences only the behaviour of bubbles with
initial radii smaller than 10(-1) mm and the rheological parameter wit
h the strongest influence on bubble collapse is the infinite-shear vis
cosity. The effect of polymer additives, including their surfactant pr
operties, on spherical bubble collapse is also discussed. (C) 1998 The
Japan Society of Fluid Mechanics and Elsevier Science B.V. All rights
reserved.