GENERATION AND CAPTURE OF METHYL(VINYL)SILANONE

Authors
BASENKO SV GEBEL IA VORONKOV MG KLYBA LV MIRSKOV RG
Citation
Sv. Basenko et al., GENERATION AND CAPTURE OF METHYL(VINYL)SILANONE, Russian chemical bulletin, 47(8), 1998, pp. 1571-1573
Citations number
6
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
47
Issue
8
Year of publication
1998
Pages
1571 - 1573
Database
ISI
SICI code
1066-5285(1998)47:8<1571:GACOM>2.0.ZU;2-R
Abstract
Methyl(vinyl)dichlorosilane reacts with DMSO in the presence of hexame thyldisiloxane to give the corresponding linear oligosiloxanes of the general formula Me3Si(OSiMeVin)(n)OSiMe3 (n = 1-6) as well as MeSi(OSi Me3)(3) and Me3Si(MeOSiVin)(m)OSi(OSiMe3)(Me)OSiMe3 (m = 1-2). The sam e reaction in the presence of chlorotrimethylsilane results in oligome rs of the general formula Me3Si(OSiMeVin)(n)Cl (n = 1-3). A possible s cheme of their formation is discussed.