To elucidate the influence on charge-exchange Spectroscopy of metastab
le deuterium donors, the corresponding cross sections for state-select
ive charge transfer have been calculated using the classical trajector
y Monte Carlo method. The cross sections for electron capture from D(n
= 2) by fully stripped low-Z ions are contrasted with those for captu
re from ground state D to indicate the importance of metastable donors
. Using the new data, effective emission coefficients for the spectral
lines of H-like light impurities used in charge-exchange spectroscopy
have been calculated. These results incorporate the presence of excit
ed n = 2 donors in the beam and apply to a wide range of neutral deute
rium beam energies. For beam energies below approximately 25 keV amu(-
1) a small fraction of D(n = 2) in the beam becomes of importance and
at lower energies it even starts to dominate the charge-exchange spect
roscopy observations.