CHROMATOGRAPHIC RESOLUTION OF RACEMIC ORGANOMETALLIC COMPOUNDS CONTAINING A CHIRAL IRON ATOM

Authors
FRANCOTTE ER BARTNICKA E PAKULSKI Z WIOENIEWSKI K ZAMOJSKI A
Citation
Er. Francotte et al., CHROMATOGRAPHIC RESOLUTION OF RACEMIC ORGANOMETALLIC COMPOUNDS CONTAINING A CHIRAL IRON ATOM, Enantiomer, 3(1), 1998, pp. 51-57
Citations number
24
Categorie Soggetti
Chemistry,"Chemistry Inorganic & Nuclear",Biology
Journal title
Enantiomer → ACNP
ISSN journal
10242430
Volume
3
Issue
1
Year of publication
1998
Pages
51 - 57
Database
ISI
SICI code
1024-2430(1998)3:1<51:CROROC>2.0.ZU;2-D
Abstract
Twelve iron(II) complexes of the ''acyliron'' type [(eta(5-)C(5)H(5))( Co)(PPh3)Fe(X), X = COR, Br, I] have been synthesized and their resolu tion into enantiomers by HPLC chromatography on chiral stationary phas es was studied. For all racemic compounds conditions permitting a good analytical resolution were elaborated and a separation of the enantio mers could be successfully achieved.