AZA-CROWN TETRATHIAFULVALENE DERIVATIVES - SYNTHESIS, X-RAY STRUCTURE, AND METAL COMPLEXATION STUDY

Authors
LEDERF F SALLE M MERCIER N BECHER J RICHOMME P GORGUES A ORDUNA J GARIN J
Citation
F. Lederf et al., AZA-CROWN TETRATHIAFULVALENE DERIVATIVES - SYNTHESIS, X-RAY STRUCTURE, AND METAL COMPLEXATION STUDY, EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, (9), 1998, pp. 1861-1865
Citations number
28
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY → ACNP
ISSN journal
1434193X
Issue
9
Year of publication
1998
Pages
1861 - 1865
Database
ISI
SICI code
1434-193X(1998):9<1861:ATD-SX>2.0.ZU;2-J
Abstract
The synthesis of new aza-macrocyclic tetrathiafulvalene (TTF) derivati ves is described, with a view to limiting the structural distortion of the redox-active TTF moiety and to favour metal complexation. An X-ra y diffraction determination of one of these crown systems is provided. The electrochemical properties of these redox-active macrocyclic liga nds are studied by cyclic voltammetry. Their complexing ability toward s silver ions is evaluated by FAB mass spectrometry.