H. Grande et al., CONFORMATIONAL RELAXATION IN CONDUCTING POLYMERS - EFFECT OF POLYMER-SOLVENT INTERACTIONS, Journal of non-crystalline solids, 235, 1998, pp. 619-622
Oxidation chronoamperograms of compacted polypyrrole films allow one t
o study the effect of the solvent on the rate of electrochemical switc
hing controlled by conformational relaxation processes. Experimental b
ehaviour has been analyzed on the basis of the electrochemically stimu
lated conformational relaxation (ESCR) model and compared to theoretic
al results extracted from free volume theories in amorphous polymers (
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