A. Mcpherson et al., MULTIPHOTON-INDUCED X-RAY-EMISSION AND AMPLIFICATION FROM CLUSTERS, Applied physics. B, Photophysics and laser chemistry, 57(5), 1993, pp. 337-347
The development of a unified picture of short-pulse high-intensity mul
tiphoton processes, embracing atoms, molecules, and solids, appears po
ssible through the study of clusters. Of particular significance are p
ossible intra-cluster processes that can influence the mechanism of io
nization and lead to the production of inner-shell vacancies. Inner-sh
ell excitation leading to prompt X-ray emission is specifically consid
ered and the treatment leads to the definition of a critical cluster s
ize n(c) representing the achievement of maximal X-ray emission from t
he ensemble. These results suggest the possibility of designing a new
class of molecular materials optimized for the efficient production an
d amplification of X-rays.