THEORETICAL-STUDY OF THE ROVIBRATIONAL ENERGY-SPECTRUM AND THE NUMBERS AND DENSITIES OF BOUND VIBRATIONAL-STATES FOR THE SYSTEM HCO+ HOC+/

Large-scale calculations of accurate energy levels for the system HCO/HOC+ in its electronic ground state are reported. The rovibrational l evels are calculated for total angular momentum J = 0, 1, and 2 by mea ns of the discrete variable representation of the angular coordinate i n conjunction with a distributed Gaussian basis for the radial degrees of freedom. A new analytical potential energy surface is used which i s based on high level ab initio calculations [CCSD(T)/cc-pVQZ]. The ro vibrational energy spectra of HCO+ and HOC+, as well as of the isotopo mers DCO+ and DOC+, are analyzed in detail up to the ground state adia batic isomerization barrier at 28 798 cm(-1). Spectroscopic parameters calculated for low lying vibrational states show distinct differences between HCO+ and HOC+. A total number of 6042 bound states up to the first classical dissociation limit (H+ + CO) at 51 621 cm(-1) and a de nsity at the threshold of 0.52/cm(-1) are estimated for J = 0. Semicla ssical phase space integration yields nearly identical results for the numbers and densities of bound states for the given surface. An empir ical model employing Morse oscillators, an explicit treatment of the h indered rotation, and stretch-bend coupling is used to simulate the qu antum mechanical data. (C) 1998 American Institute of Physics.