P. Werle et al., NEAR-INFRARED TRACE-GAS SENSORS BASED ON ROOM-TEMPERATURE DIODE-LASERS, Applied physics. B, Lasers and optics, 67(3), 1998, pp. 307-315
Semiconductor lasers continue to find an increasing number of applicat
ions as tunable sources for high-resolution spectroscopy. Substantial
improvements in sensitivity and detection speed have been achieved and
many laser-based gas monitoring applications have been reported. In t
his paper the relevant characteristics of currently available semicond
uctor lasers with respect to spectroscopic gas analysis will be discus
sed. Experimental data from a CO2 monitor designed for field applicati
ons using room-temperature diode lasers are presented. Near-infrared D
EB lasers operating at 1.57 mu m and around 2.0 mu m have been used fo
r CO2 measurements. At ambient concentration levels a resolution of mo
re than two orders of magnitude has been demonstrated at 1.57 mu m, at
2 mu m the precision is in the order of 0.1 ppm CO2, and for trace an
alysis a detection limit of 10 ppb has been obtained. The measurements
demonstrate the capability of near-infrared DFB diode lasers for the
precise determination of CO2 concentrations as required for climatolog
ical, medical, or industrial applications.