POLY[BIS(ETHYLGLYCOXYPROPYL)SILYLENE]S AND POLY[N-ALKYL(ETHYLGLYCOXY)SILYLENE]S AND THEIR HIGHER HOMOLOGS, 1 - MONOMER SYNTHESIS AND POLYMERIZATION

Citation
La. Schwegler et M. Moller, POLY[BIS(ETHYLGLYCOXYPROPYL)SILYLENE]S AND POLY[N-ALKYL(ETHYLGLYCOXY)SILYLENE]S AND THEIR HIGHER HOMOLOGS, 1 - MONOMER SYNTHESIS AND POLYMERIZATION, Macromolecular chemistry and physics, 199(9), 1998, pp. 1859-1864
Citations number
23
Categorie Soggetti
Polymer Sciences
ISSN journal
10221352
Volume
199
Issue
9
Year of publication
1998
Pages
1859 - 1864
Database
ISI
SICI code
1022-1352(1998)199:9<1859:PAP>2.0.ZU;2-J
Abstract
Dichlorosilanes with ethyloligoglycoxypropyl substituents were synthes ized from dichlorosilane and the respective allyl compounds. Wurtz-typ e coupling reaction led to a series of ether substituted polysilylenes with a distinct amphiphilic character. Formation of high molecular we ight polymers becomes increasingly difficult as the length of the ethe r substituents is increased.