ASYMMETRIC ALLYLATION - AN EFFECTIVE STRATEGY FOR THE CONVERGENT SYNTHESIS OF HIGHLY FUNCTIONALIZED HOMOALLYLIC ALCOHOLS

Authors
WILLIAMS DR BROOKS DA MEYER KG CLARK MP
Citation
Dr. Williams et al., ASYMMETRIC ALLYLATION - AN EFFECTIVE STRATEGY FOR THE CONVERGENT SYNTHESIS OF HIGHLY FUNCTIONALIZED HOMOALLYLIC ALCOHOLS, Tetrahedron letters, 39(40), 1998, pp. 7251-7254
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
40
Year of publication
1998
Pages
7251 - 7254
Database
ISI
SICI code
0040-4039(1998)39:40<7251:AA-AES>2.0.ZU;2-#
Abstract
A survey of stereoselective syntheses of highly-functionalized homoall ylic alcohols is described via asymmetric allylation. initial transmet alation from an allylic stannane to a C-2 symmetric chiral borane cont roller is followed by low temperature addition to aldehydes efficientl y effecting convergent strategies to complex targets. (C) 1998 Elsevie r Science Ltd. All rights reserved.