We present a detailed analysis of carrier-induced modifications on the
spatial band diagrams of In-Ga-As/In-Ga-As-P separate-confinement mul
tiple-quantum-well structures and its consequences on optical properti
es. In the high-carrier-density regime, we observe experimentally a se
cond peak in the spectra of the optical gain. This can be understood b
y a buildup of a space charge and band bending which is caused by a sp
atial separation between electrons and holes due to the different dens
ity of states of the conduction and valence bands. This band bending c
auses a localization of barrier conduction-band states in the quantum-
well region and an enhancement of the overlap integral of those states
with quantized heavy-hole states giving rise to substantial modificat
ions in the optical matrix elements. These modified matrix elements ar
e the origin of the new class of optical transitions observed in the o
ptical gain spectra.