RHODIUM-MEDIATED SILYLATIVE CYCLIZATION OF 1,6-HEPTADIYNES

Authors
MURAOKA T MATSUDA I ITOH K
Citation
T. Muraoka et al., RHODIUM-MEDIATED SILYLATIVE CYCLIZATION OF 1,6-HEPTADIYNES, Tetrahedron letters, 39(40), 1998, pp. 7325-7328
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
40
Year of publication
1998
Pages
7325 - 7328
Database
ISI
SICI code
0040-4039(1998)39:40<7325:RSCO1>2.0.ZU;2-J
Abstract
RhCl(PPh3)(3) readily reacts with an equivalent mole of a hydrosilane to form the Si-Rh-H species that plays an important role in the silyla tive cyclization of 1,6-heptadiynes to construct 1,2-dialkylidenecyclo pentane derivatives. (C) 1998 Elsevier Science Ltd. All rights reserve d.