F. Koksal et I. Kartal, EPR OF GAMMA-IRRADIATED (CH3)(3)NHCLO4, (CH3)(3)NHBF4 AND [(CH3)(4)N](2)ZNCL4 SINGLE-CRYSTALS, Radiation physics and chemistry (1993), 53(5), 1998, pp. 501-504
Citations number
10
Categorie Soggetti
Nuclear Sciences & Tecnology","Chemistry Physical","Physics, Atomic, Molecular & Chemical
Gamma irradiation damage centres in (CH3)(3)NHClO4, (CH3)(3)NHBF4 and
[(CH3)(4)N](2)ZnCl4 were investigated by electron paramagnetic resonan
ce spectroscopy at room temperature. The centres were found to be (CH3
)(3)N+. and the hyperfine structure parameters for methyl protons and
the nitrogen nucleus were determined aerermlned. The results indicated
that the (CH3)(3)N+. radical wholly performs reorientational motions
around its C-3v axis in addition to the reorientatonal motions of the
methyl groups around their C-3v axes. These results were compared with
the earlier studies on (CH3)(3)N+. radical and discussed. Low tempera
ture measurements on the first two of the title compounds were assesse
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