J. Barclay et al., EXPERIMENTAL PHASE-EQUILIBRIA CONSTRAINTS ON PRE-ERUPTIVE STORAGE-CONDITIONS OF THE SOUFRIERE HILLS MAGMA, Geophysical research letters, 25(18), 1998, pp. 3437-3440
New experimental results are used to constrain the P, T, X(H2O) condit
ions of the Soufriere Hills magma prior to ascent and eruption. The ex
periments were performed on a powdered andesite erupted in January, 19
96, at an fO(2) corresponding to similar to NNO+1 with P-H2O and tempe
ratures in the range 50 to 200 MPa and 800 to 940 degrees C. Amphibole
is stable at P-H2O >115 MPa and temperatures <875 degrees C. Quartz o
nly becomes stable at low temperatures and after high degrees of cryst
allization (T <840 degrees C, >72 wt% SiO2 in residual melt) at P-H2O
>115 MPa. Analyses of rhyolitic glass inclusions in quartz and plagioc
lase from recently erupted samples indicate melt water contents of 4.2
7 +/- 0.54 wt% H2O and CO2 contents <60 ppm. The evolved Soufriere Hil
ls magma would therefore be H2O-saturated at pressures <130 MPa. These
results suggest that the Soufriere Hills magma containing the stable
assemblage amphibole, quartz, plagioclase, orthopyroxene, magnetite an
d ilmenite was stored at P-H2O of 115-130 MPa, equivalent to a minimum
depth for a water-saturated magma chamber of 5-6 km depth. Magma temp
eratures were initially low (820-840 degrees C). Quartz is believed to
have been destabilised by a heating event involving injection of new
basaltic magma. The stability field of hornblende provides a useful up
per limit (similar to 880 degrees C) for the extent of this reheating.