R. Argazzi et al., EFFICIENT LIGHT-TO-ELECTRICAL ENERGY-CONVERSION WITH DITHIOCARBAMATE RUTHENIUM POLYPYRIDYL SENSITIZERS, Inorganic chemistry, 37(18), 1998, pp. 4533-4537
New Ru(dcbH)(dcbH(2)(L) sensitizers, where L is diethyldithiocarbamate
, dibenzyldithiocarbamate, or pyrrolidinedithiocarbamate, dcbH is 4-(C
OOH)-4'-(COO-)-2,2'-bipyridine, and dcbH(2) is 4,4'-(COOH)(2)-2,2'-bip
yridine, have been synthesized, characterized, and anchored to nanocry
stalline TiO2 films for light to electrical energy conversion in regen
erative photoelectrochemical cells with I-/I-2 acetonitrile electrolyt
e. The sensitizers have intense metal-to-ligand charge-transfer (MLCT)
bands centered similar to 380 and 535 nm that sensitize TiO2 over a n
otably broad spectral range. The photophysical and photoelectrochemica
l studies of these materials are contrasted with cis-Ru(dcbH(2))(2)(NC
S)(2), which is one of the most efficient sensitizers reported to date
. Photophysical measurements show that the high photocurrent observed
for cis-Ru(dcb)(2)(NCS)(2)/TiO2 is due to efficient and rapid iodide o
xidation.