Yr. Lee et al., SILVER(I) CELITE PROMOTED OXIDATIVE CYCLOADDITION OF 4-HYDROXYCOUMARIN TO OLEFINS - A FACILE SYNTHESIS OF DIHYDROFUROCOUMARINS AND FUROCOUMARINS/, Tetrahedron, 54(40), 1998, pp. 12215-12222
An efficient synthesis of dihydrofurocoumarins and furocoumarins is ac
hieved from 4-hydroxycoumarins and olefins in the presence of Ag2CO3/C
elite in moderate yields. The new method has been applied to the synth
esis of the natural cyclobrachycoumarin isolated from Brachyclados meg
alanthus. (C) 1998 Elsevier Science Ltd. All rights reserved.