SYNTHESIS AND CHARACTERIZATION OF BIS(FERROCENYLETHYNYL) COMPLEXES OFPLATINUM(II) - A REINVESTIGATION OF THEIR ELECTROCHEMICAL-BEHAVIOR

Citation
D. Osella et al., SYNTHESIS AND CHARACTERIZATION OF BIS(FERROCENYLETHYNYL) COMPLEXES OFPLATINUM(II) - A REINVESTIGATION OF THEIR ELECTROCHEMICAL-BEHAVIOR, INORGANIC CHEMISTRY COMMUNICATIONS, 1(7), 1998, pp. 239-245
Citations number
30
Categorie Soggetti
Chemistry Inorganic & Nuclear
ISSN journal
13877003
Volume
1
Issue
7
Year of publication
1998
Pages
239 - 245
Database
ISI
SICI code
1387-7003(1998)1:7<239:SACOBC>2.0.ZU;2-9
Abstract
We describe herein the synthesis and the electrochemical behaviour of a series of bis( ferrocenylethynyl) complexes of platinum( II). In all complexes, the electronic interaction between the redox-active iron c ores of the ferrocenyl termini is small, indicating a moderate electro nic delocalisation over the bis( cyclopentadienyl-acetylide) Pt chain. (C) 1998 Elsevier Science S.A. All rights reserved.