C-F BOND ACTIVATION IN PERFLUOROBENZOTHIOLATE COMPOUNDS OF OS(III) - X-RAY STRUCTURES OF [OS(SC6F4(F-2))(SC6F5)(2)(PME2PH)(2)], [OS(SC6F5)(2)(O-S2C6F4)(PME2PH)] AND [OS(C6F5)(2)(O-S2C6F4)(PME2PH)(2)]

Authors
ARROYO M BERNES S BRIANZO JL MAYORAL E RICHARDS RL RIUS J TORRENS H
Citation
M. Arroyo et al., C-F BOND ACTIVATION IN PERFLUOROBENZOTHIOLATE COMPOUNDS OF OS(III) - X-RAY STRUCTURES OF [OS(SC6F4(F-2))(SC6F5)(2)(PME2PH)(2)], [OS(SC6F5)(2)(O-S2C6F4)(PME2PH)] AND [OS(C6F5)(2)(O-S2C6F4)(PME2PH)(2)], INORGANIC CHEMISTRY COMMUNICATIONS, 1(7), 1998, pp. 273-276
Citations number
27
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS → ACNP
ISSN journal
13877003
Volume
1
Issue
7
Year of publication
1998
Pages
273 - 276
Database
ISI
SICI code
1387-7003(1998)1:7<273:CBAIPC>2.0.ZU;2-M
Abstract
Thermolysis of [Os(SC6F4(F-2)) (SC6F5)(2)(PMe2Ph)(2)] (1) in refluxing toluene affords [Os(SC6F5)(2)(o-S2C6F4) (PMe2Ph)] (2) and [Os(C6F5)(2 )(o-S2C6F4) (PMe2Ph)(2)] (3) through a process involving C-F cleavage as well as C-S bond formation. The X-ray structures of 1, 2 and 3 have been determined. In the solid state compound 1 shows a C-F --> Os int eraction. (C) 1998 Elsevier Science S.A. All rights reserved.