SYMMETRICAL TRIS(4,6-DIAMINO-5-METHYLENE-2-PYRIMIDONES) - NEW BUILDING-BLOCKS FOR SELF-ASSEMBLY OF HOLLOW SPHERICAL SUPRAMOLECULES LOCKED BY HYDROGEN-BONDS

Authors
ALEXANDER D HOLY P FIEDLER P HAVLAS Z ZAVADA J
Citation
D. Alexander et al., SYMMETRICAL TRIS(4,6-DIAMINO-5-METHYLENE-2-PYRIMIDONES) - NEW BUILDING-BLOCKS FOR SELF-ASSEMBLY OF HOLLOW SPHERICAL SUPRAMOLECULES LOCKED BY HYDROGEN-BONDS, Collection of Czechoslovak Chemical Communications, 61(10), 1996, pp. 1464-1472
Citations number
22
Categorie Soggetti
Chemistry
Journal title
Collection of Czechoslovak Chemical Communications → ACNP
ISSN journal
00100765
Volume
61
Issue
10
Year of publication
1996
Pages
1464 - 1472
Database
ISI
SICI code
0010-0765(1996)61:10<1464:ST-NB>2.0.ZU;2-N
Abstract
Concise synthesis of the tris(pyrimidones) 1a,b is described. Molecula r modeling study demonstrated that both the prepared models 1a,b ale c apable of self-assembling under formation of spherical dimers locked b y 18 hydrogen bonds. Extreme insolubility in ail common solvents precl uded investigation of the self-assembly in solution. Circumstantial ev idence in favor of the self-assembly has been provided in the solid an d gas phase.