The use of a diffraction spectrometer developed by Deslattes for the d
etermination of mammographic kV is extended to the measurement of accu
rate, relative x-ray spectra. Raw x-ray spectra (photon fluence versus
energy) are determined by passing an x-ray beam through a bent quartz
diffraction crystal, and the diffracted x-rays are detected by an x-r
ay intensifying screen coupled to a charge coupled device. Two nonline
ar correction procedures, one operating on the energy axis and the oth
er operating on the fluence axis, are described and performed on measu
red x-ray spectra. The corrected x-ray spectra are compared against ta
bulated x-ray spectra measured under nearly identical conditions. Resu
lts indicate that the current device is capable of producing accurate
relative x-ray spectral measurements in the energy region from 12 keV
to 40 keV, which represents most of the screen-film mammography energy
range. Twelve keV is the low-energy cut-off, due to the design geomet
ry of the device. The spectrometer was also used to determine the ener
gy-dependent x-ray mass attenuation coefficients for aluminium, with e
xcellent results in the 12-30 keV range. Additional utility of the dev
ice for accurately determining the attenuation characteristics of vari
ous normal and abnormal breast tissues and phantom substitutes is anti
cipated.