RELATIVE STABILITY OF MULTIPLE STATIONARY STATES RELATED TO FLUCTUATIONS

Authors
Citation
Nf. Hansen et J. Ross, RELATIVE STABILITY OF MULTIPLE STATIONARY STATES RELATED TO FLUCTUATIONS, The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory, 102(36), 1998, pp. 7123-7126
Citations number
19
Categorie Soggetti
Chemistry Physical
ISSN journal
10895639
Volume
102
Issue
36
Year of publication
1998
Pages
7123 - 7126
Database
ISI
SICI code
1089-5639(1998)102:36<7123:RSOMSS>2.0.ZU;2-5
Abstract
We apply the eikonal approximation to the stochastic master equation f or reaction-diffusion systems. Its stationary solution is expressed as an excess work, and is shown to be a Lyapunov function for the determ inistic evolution of inhomogeneous systems. From this result we establ ish a new stochastic criterion of relative stability and equistability of systems with multiple homogeneous stationary states in terms of in homogeneous fluctuations.