Ep. Prokopev et Vp. Shantarovich, OPTICAL-MODEL OF POSITRON AND EFFECTIVE CHARGES OF OXYGEN IONS IN METAL-OXIDES, Chemical physics reports, 17(4), 1998, pp. 629-635
The optical positron model allowing for the positron repulsion by a nu
clear Coulomb field in the Landau-Lifshitz approximation is invoked to
derive an equation for calculating the effective charges eta(-e) of o
xygen ions in metal oxides (a) from measured half-widths Gamma (mrad)
of angular distributions of annihilation photons arising in crystals b
y two-quantum annihilation of positrons from bound states of positronanion systems and (b) from short lifetimes tau(1) of annihilation time
distributions. Effective charges of oxygen ions calculated for a rich
variety of metal oxides agree with their literature values gained by
non-positron methods to within the scatter in these values. Effective
charges calculated by the ''positron'' method vary in the series of ox
ides in much the same way as their ''non-positron'' counterparts. The
calculated ''positron'' effective charges of oxygen ions in metal oxid
es may serve as reference data in solving theoretical and applied prob
lems in physics and chemistry of solids and various problems of materi
als science.