CALCULATION OF SHOCK COMPRESSION PARAMETERS FOR CHLORINATED METHANES

Authors
DREMOV VV MODESTOV DG
Citation
Vv. Dremov et Dg. Modestov, CALCULATION OF SHOCK COMPRESSION PARAMETERS FOR CHLORINATED METHANES, Chemical physics reports, 17(4), 1998, pp. 781-790
Citations number
8
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
Chemical physics reports → ACNP
ISSN journal
10741550
Volume
17
Issue
4
Year of publication
1998
Pages
781 - 790
Database
ISI
SICI code
1074-1550(1998)17:4<781:COSCPF>2.0.ZU;2-U
Abstract
A model equation of state of chlorinated methane derivatives allowing for their dissociation is constructed using the single-liquid van der Waals model and variational theory of equations of state suggested for dense gases. A comparison of the calculated shock Hugoniots with expe riment shows the effect of relaxation processes(namely, of slow dissoc iation relaxation) on the shape of shock Hugoniot. Incorporation in th e model of a finite dissociation rate yielded good agreement with the experimental data.