SYNTHESIS OF BILIN-1,19-DIONES AND BILADIENE-AC-1,19-DIONES WITH C(10) ADAMANTYL AND TERT-BUTYL GROUPS

Authors
KAR AK LIGHTNER DA
Citation
Ak. Kar et Da. Lightner, SYNTHESIS OF BILIN-1,19-DIONES AND BILADIENE-AC-1,19-DIONES WITH C(10) ADAMANTYL AND TERT-BUTYL GROUPS, Journal of heterocyclic chemistry, 35(4), 1998, pp. 795-803
Citations number
25
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of heterocyclic chemistry → ACNP
ISSN journal
0022152X
Volume
35
Issue
4
Year of publication
1998
Pages
795 - 803
Database
ISI
SICI code
0022-152X(1998)35:4<795:SOBABW>2.0.ZU;2-E
Abstract
Bilirubin and biliverdin analogs bearing bulky adamantyl and tert-buty l groups at the central C(10) position were synthesized and their stru ctures were analyzed by nmr and ultraviolet-visible spectroscopy and b y molecular mechanics calculations, all of which collectively indicate d a preference for helical conformations.