DIELS-ALDER REACTIONS OF C-PHENYLATED SILOLES WITH 1,4-EPOXY-1,4-DIHYDRONAPHTHALENE

Citation
Si. Kirin et al., DIELS-ALDER REACTIONS OF C-PHENYLATED SILOLES WITH 1,4-EPOXY-1,4-DIHYDRONAPHTHALENE, Journal of organometallic chemistry, 566(1-2), 1998, pp. 85-91
Citations number
40
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
ISSN journal
0022328X
Volume
566
Issue
1-2
Year of publication
1998
Pages
85 - 91
Database
ISI
SICI code
0022-328X(1998)566:1-2<85:DROCSW>2.0.ZU;2-E
Abstract
Preparation of a novel type of cycloadducts composed of a 7-silanorbor nene ring condensed to the 7-oxanorbornene moiety (5-7) is described a nd their spectroscopic features are discussed in detail. The X-ray dat a for 5 are also presented. Finally, formation of silanole 8 by nucleo philic cleavage of an endocyclic silicon-carbon bond in 7 is described . (C) 1998 Elsevier Science S.A. All rights reserved.