LASER-INDUCED DECOMPOSITION OF SILACYCLOBUTANE - EXTENSIVE H(SI) H(C)SCRAMBLING VIA 1,2-H SHIFT IN SILENE AND RADICAL REACTIONS/

Authors
KHACHATRYAN L VOLNINA EA FAJGAR R POLA J
Citation
L. Khachatryan et al., LASER-INDUCED DECOMPOSITION OF SILACYCLOBUTANE - EXTENSIVE H(SI) H(C)SCRAMBLING VIA 1,2-H SHIFT IN SILENE AND RADICAL REACTIONS/, Journal of organometallic chemistry, 566(1-2), 1998, pp. 263-270
Citations number
41
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
566
Issue
1-2
Year of publication
1998
Pages
263 - 270
Database
ISI
SICI code
0022-328X(1998)566:1-2<263:LDOS-E>2.0.ZU;2-5
Abstract
The mechanism of the silacyclobutane decomposition has been further re fined through a study of the laser induced decomposition of 1,1-dideut erio-1-silacyclobutane. It is concluded that the identified volatile a nd solid products and the hydrogen and deuterium content in them are i n accord with 1,2-H(D)-shift in intermediate silene and with radical r eactions. (C) 1998 Elsevier Science S.A. All rights reserved.