PHOSPHENIUM COMPLEXES - 39 - CYCLOADDITION REACTIONS OF MOLYBDENUM AND TUNGSTEN PHOSPHENIUM COMPLEXES WITH DIAZOETHYL ACETATE - SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF 2-MEMBERED AND 3-MEMBERED PHOSPHAMETALLACYCLES

Authors
MALISCH W GRUN K FRIED A REICH W PFISTER H HUTTER G ZSOLNAI L
Citation
W. Malisch et al., PHOSPHENIUM COMPLEXES - 39 - CYCLOADDITION REACTIONS OF MOLYBDENUM AND TUNGSTEN PHOSPHENIUM COMPLEXES WITH DIAZOETHYL ACETATE - SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF 2-MEMBERED AND 3-MEMBERED PHOSPHAMETALLACYCLES, Journal of organometallic chemistry, 566(1-2), 1998, pp. 271-276
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
566
Issue
1-2
Year of publication
1998
Pages
271 - 276
Database
ISI
SICI code
0022-328X(1998)566:1-2<271:PC-3-C>2.0.ZU;2-Z
Abstract
The phosphenium complexes Cp(OC)(2)M=P(t-Bu)(2) (M=Mo, W) (1a,b) react with diazoethylacetate (2) to yield the five-membered phosphametallac ycles Cp(OC)(2)M-P(t-Bu)(2)-N(H)-N=C(CO2Et) (4a,b). From Cp(OC)(2)W=P( Ph)(Mes) (5) and 2 the nitrogen-free three-membered phosphametallacycl e Cp(OC)(2)W-P(Ph)(Mes)-C(H)CO2Et (6) is obtained. The structures of 4 b and 6 were determined by X-ray analysis.